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It is located in the valley of the Chillán River, between Curicó and Talca. According to the 2002 census of the National Statistics Institute, Molina spans an area of and has 33,857 inhabitants (18,927 men and 14,930 women). Of these, 29.2% lived in urban areas and 70.8% in rural areas. The population grew by 13% (4124 persons) between 1992 and 2002.